You may discover that the operating system requirements are not automatically selected when you add a Microsoft Application Virtualization 4.x application for Windows 8 or Windows 8.1 as a package in the System Center 2012 Configuration Manager Administrator console. If you see this, we have a work around detailed in the article below.
KB3070370 - App-V 4.x apps don't set Windows 8 deployment requirements in System Center 2012 Configuration Manager SP1 (https://support.microsoft.com/en-us/kb/3070370)
J.C. Hornbeck| Solution Asset PM | Microsoft GBS Management and Security Division
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ConfigMgr 2012 R2 App-V 4.x